Poly[[(μ3-adamantane-1,3-diacetato)[ μ-N-(pyridin-3-yl)isonicotinamide]nickel(II)] monohydrate], A Layered Coordination Polymer with Triangular (3,6) Topology
Document Type
Article
Publication Date
10-5-2023
Publication Source
Iucrdata
Volume Number
8
Issue Number
10
E-ISSN
24143146
Article Number
x230869
Abstract
The title compound, {[Ni(C14H18O4)(C11H9N3O)] H2O}n, contains octahedrally coordinated NiII ions ligated by 1,3-adamantanediacetato (ada) ligands and N-(pyridin-3-yl)isonicotinamide (3-pina) ligands, to form coordination polymer layers with a triangular (3,6) grid topology based on [Ni2(OCO)2] dimeric units. The diperiodic layer motifs stack in an ABAB pattern mediated by C-H O supramolecular interactions between ada ligands and water molecules of crystallization to form the full triperiodic crystal structure of the title compound.
Recommended Citation
Published in: Iucrdata, Volume 8, Issue 10, October 5, 2023.
COinS
